PHP is a managed language. On the userspace side of things, this careful control of resources and memory means easier prototyping and fewer crashes. After you delve under the hood though, all bets are off and it's up to the responsible developer to maintain the integrity of the runtime environment.
The PHP Life Cycle
Variables from the Inside Out
Memory Management
Setting Up a Build Environment
Your First Extension
Returning Values
Accepting Parameters
Working with Arrays and HashTables
The Resource Data Type
PHP4 Objects
PHP5 Objects
Startup, Shutdown, and a Few Points in Between
INI Settings
Accessing Streams
Implementing Streams
Diverting the Stream
Configuration and Linking
Extension Generators
Setting Up a Host Environment
Advanced Embedding
Appendix A. A Zend API Reference
Appendix B. PHPAPI
Appendix C. Extending and Embedding Cookbook
Appendix D. Additional Resources