In SSRS 2005, three options are available to sort results on a report:
Make the data source (database) sort data on data retrieval by using an ORDER BY clause.
Make SSRS sort data during report generation. SSRS sorts items that have the Sorting property defined.
Use the new, interactive sort functionality for HTML-rendered reports only. This functionality makes SSRS regenerate a report with a new direction: ascending or descending.