Stories have loads of hidden assumptions. The ones to worry about are those that will cause problems.
To identify the potential problems:
Think about the system from the customer's viewpoint.
Think about the system from the programmer's viewpoint.
Identify the mismatches.
Expect to ask lots of questions, but be disciplined. There's a limit.
Ask tangential but targeted questions that allow the respondent to make connections and think of the details.
OK, now it's your turn to try these ideas out with an exercise.